134756-66-4

Basic information

• Product Name: 3,6-di-O-benzyl-(-)-allosamizoline
• Synonyms: 3,6-di-O-benzyl-(-)-allosamizoline
• CAS NO: 134756-66-4
• Molecular Weight: 396.486
• Mol File: 134756-66-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3,6-di-O-benzyl-(-)-allosamizoline(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6-di-O-benzyl-(-)-allosamizoline(134756-66-4)
• EPA Substance Registry System: 3,6-di-O-benzyl-(-)-allosamizoline(134756-66-4)

Safety Data

• Hazardous Substances Data: 134756-66-4(Hazardous Substances Data)

Upstream product

• 158226-48-3 [(3aS,4R,5R,6S,6aS)-4-Benzyloxy-6-benzyloxymethyl-5-(tert-butyl-dimethyl-silanyloxy)-4,5,6,6a-tetrahydro-3aH-cyclopentaoxazol-2-yl]-dimethyl-amine 
• 124583-63-7 ((1bS,4aS,5S)-5-Benzyloxymethyl-1b,4a,5,5a-tetrahydro-1aH-1,4-dioxa-2-aza-cyclopropa[a]pentalen-3-yl)-dimethyl-amine 
• 139573-30-1 [(3aS,4R,5R,6S,6aS)-4-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2-dimethylamino-4,5,6,6a-tetrahydro-3aH-cyclopentaoxazol-6-yl]-methanol 
• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 
• 134756-64-2 <1(R)-(1α,4α,5β)>-5-<(benzyloxy)methyl>-4-<(tert-butyldimethylsilyl)oxy>-2-cyclopenten-1-ol carbamate 
• 174810-43-6 Acetic acid (1R,4S,5S)-5-benzyloxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-cyclopent-2-enyl ester 
• 134756-61-9 (1α,2β,3α)-2-<(benzyloxy)methyl>-4-cyclopentene-1,3-diol diacetate 
• 134756-63-1 <1(R)-(1α,4α,5β)>-5-<(benzyloxy)methyl>-4-<(tert-butyldimethylsilyl)oxy>-2-cyclopenten-1-ol 
• 134756-65-3 <1(R)-(1α,2β,3α)>-2-<(benzyloxy)methyl>-4-cyclopentene-1,3-diol monocarbamate 
• 134875-87-9 <3a(R)-(3aα,6α,6aα)>-6-<(benzyloxy)methyl>-3,6a-dihydro-N,N-dimethyl-6H-cyclopentoxazol-2-amine 
• 134756-62-0 <1(S)-(1α,4α,5β)>-4-(acetyloxy)-5-<(benzyloxy)methyl>-2-cyclopenten-1-ol 
• 134875-85-7 <3a(R)-(3aα,6α,6aα)>-6-<(benzyloxy)methyl>-3,3a,6,6a-tetrahydro-2H-cyclopentoxazol-2-one 
• 100021-11-2 (1α,2β,3α)-2-(benzyloxymethyl)cyclopent-4-ene-1,3-diol 
• 252055-35-9 3-O-benzyl-4,6-di-O-1,1,3,3-tetraisopropyldisiloxane-allosamizoline 

Downstream Products

• 144539-85-5 allosamidin 
• 134756-69-7 O-<2-benzenesulfonamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-D-allopyranosyl>-β-(1->4)-O-<2-benzenesulfonamido-6-O-benzyl-2-deoxy-3-O-<<2-(trimethylsilyl)ethoxy>methyl>-D-allopyranosyl>-β-(1->4)-3,6-di-O-benzyl-(-)-allosamizoline 

Relevant articles and documents

Preparation of 3,6-di-O-benzylallosamizoline from natural allosamidin

Preparation of 3,6-di-O-benzylallosamizoline, the aglycon required for the total synthesis of allosamidin and its related compounds, from natural allosamizoline obtained from natural allosamidin is described. Copyright (C) 2000 Elsevier Science Ltd.

Total synthesis of (-)-allosamidin, an insect chitinase inhibitor, employing chitin as a key starting material

(-)-Allosamidin (1), a novel insect chitinase inhibitor, was stereoselectively synthesized from di- and monosaccharidic constituents of chitin, N,N'-diacetylchitobiose (2) and D-glucosamine (3).