1347753-74-5Relevant articles and documents
Regio- and enantioselective Pd-catalyzed allylic amination of monosubsti-tuted allylic substrates with BocNHOMe
Zheng, Bao-Hui,Ding, Chang-Hua,Hou, Xue-Long
supporting information; experimental part, p. 2262 - 2264 (2011/10/19)
A new type of N-nucleophile has been developed in Pd-catalyzed asymmetric allylic amination with monosubstituted allyl substrates, affording corresponding branched allyl amines in high regio- and enantioselectivities. Either OMe or Boc group in products can be removed easily to provide primary amine derivatives with the optical purity unchanged. Georg Thieme Verlag Stuttgart - New York.
