13478-28-9Relevant academic research and scientific papers
Thermodynamic data of the dimerisation of gaseous CrI2(g), MnI2(g), FeI2(g), and CoI2(g), experimental and quantum chemical investigations
Schiefenhoevel,Binnewies,Janetzko,Jug
, p. 1513 - 1517 (2008/10/08)
By means of quantum chemical methods molar heats and entropies as a function of temperature for the monomeric and dimeric diiodides of 3d-metals have been calculated. From mass-spectrometric measurements of the dimerisation equilibria of gaseous CrI2, MnI2, FeI2, and CoI2 using the Knudsen-effusion method the heats of dimerisation and the heats of formation of the monomeric and dimeric iodides could be derived using the results of the quantum chemical calculations. WILEY-VCH Verlag GmbH, 2001.
