134833-67-3Relevant academic research and scientific papers
METAL-ASSISTED REACTIONS. PART 22. SYNTHESIS OF PERHALOGENATED PORPHYRINS AND THEIR USE AS OXIDATION CATALYSTS
Gonsalves, Antonio M. d'A. Rocha,Johnstone, Robert A. W.,Pereira, Mariette M.,Shaw, Jaqueline,Sobral, Abilio J. F. do N.
, p. 1355 - 1358 (1991)
Meso-tetrakisarylporphyrins have been perchlorinated and perbrominated at peripheral (β)-positions of the pyrrole rings by high-yielding procedures.These halogenated porphyrins show enhanced catalytic activity towards oxidation of alkanes and alkenes but
USE OF METALLOPORPHYRINS AND SALEN COMPLEXES FOR THE CATALYTIC OXIDATION OF ORGANIC COMPOUNDS
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, (2013/08/28)
A method of decomposing an organic substrate includes identifying an organic substrate or its constituents having one or more desired or undesired properties; and contacting the organic substrate with an oxidizing agent and a catalyst selected from the group consisting of sterically hindered and electronically activated metallotetraphenylporphyrms, metallophthalocyanines and metallosalen complexes in an aqueous or aqueous-organic solution to produce a treated composition comprising one or more degradation products, wherein the degradation products have one or more desired properties and/or lack the undesired properties of the organic substrate.
Porphyrins bearing halogens at the meso-phenyl and β-pyrrolic positions: Synthesis and spectral propertiest
Wijesekera, Tilak,Dupre, Daniel,Cader, Mohamed S.R.,Dolphin, David
, p. 765 - 775 (2007/10/03)
The synthesis of symmetrical porphyrins chlorinated at both ortho positions of the meso-aryl substituents, and the chlorination and bromination of the β-pyrrole positions is reported. The β-chlorination of meso-tetraphenylporphyrin via its nickel(II) comp
