134860-57-4

Basic information

• Product Name: (1S,2S,4R)-5-Benzyloxy-1-(4,5-dimethyl-furan-2-yl)-1-hydroxy-2,4-dimethyl-pentan-3-one
• Synonyms: (1S,2S,4R)-5-Benzyloxy-1-(4,5-dimethyl-furan-2-yl)-1-hydroxy-2,4-dimethyl-pentan-3-one
• CAS NO: 134860-57-4
• Molecular Weight: 330.424
• Mol File: 134860-57-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2S,4R)-5-Benzyloxy-1-(4,5-dimethyl-furan-2-yl)-1-hydroxy-2,4-dimethyl-pentan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S,4R)-5-Benzyloxy-1-(4,5-dimethyl-furan-2-yl)-1-hydroxy-2,4-dimethyl-pentan-3-one(134860-57-4)
• EPA Substance Registry System: (1S,2S,4R)-5-Benzyloxy-1-(4,5-dimethyl-furan-2-yl)-1-hydroxy-2,4-dimethyl-pentan-3-one(134860-57-4)

Safety Data

• Hazardous Substances Data: 134860-57-4(Hazardous Substances Data)

Upstream product

• 52480-43-0 4,5-dimethyl-2-formylfuran 
• 134860-59-6 C₃₃H₅₁BO₂ 

Downstream Products

• 97806-83-2 (S)-2-[(1S,2R,3R)-4-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-1,3-dimethyl-butyl]-6-hydroxy-5,6-dimethyl-6H-pyran-3-one 
• 85828-13-3 (1S,2S,3R,4R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-1-(4,5-dimethyl-furan-2-yl)-2,4-dimethyl-pentan-1-ol 
• 134860-60-9 (S)-2-((1R,2R,3R)-4-Benzyloxy-2-hydroxy-1,3-dimethyl-butyl)-6-hydroxy-5,6-dimethyl-6H-pyran-3-one 
• 134931-85-4 (1S,3R,4R,5S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-1,4,8-trimethyl-2,9-dioxa-bicyclo[3.3.1]non-7-en-6-one 
• 134860-58-5 (1S,2R,3R,4R)-5-Benzyloxy-1-(4,5-dimethyl-furan-2-yl)-2,4-dimethyl-pentane-1,3-diol 

Relevant articles and documents

ASYMMETRIC ALDOL REACTIONS USING CHIRAL BORON REAGENTS: APPLICATION TO THE SYNTHESIS OF TIRANDAMYCIN A

The bicyclic acetal 1, a key intermediate in previous synthetic studies on tirandamycin A, has been prepared in enantiomerically pure form starting from the (R)-ethylketone 2 and the aldehyde 3.A reagent controlled aldol reaction using (-)-(Ipc)2BOTf sele