134870-83-0Relevant articles and documents
Unusual 1,3-Rearrangement of Trimethylsilyl Group in the Reaction of 2,4,6-Trisphenyllithium
Tokitoh, Norihiro,Matsumoto, Tsuyoshi,Suzuki, Hiroyuki,Okazaki, Renji
, p. 2049 - 2052 (1991)
2,4,6-Trisphenyllithium (TbLi) gave a novel 1,3-silicon rearrangement product above -30 deg C, while the treatment of TbLi with some electrophiles also afforded 1,3-silicon rearrangement products even at -78 deg C probably via single electron transfer mechanism.