Unusual 1,3-Rearrangement of Trimethylsilyl Group in the Reaction of 2,4,6-Trisphenyllithium

DOI: 10.1016/S0040-4039(00)78905-2

Source and publish data:

Tetrahedron Letters p. 2049 - 2052 (1991)

Update date:2022-07-30

Topics: Reaction Experimental Trimethylsilyl Phenyllithium

Authors:

Tokitoh, Norihiro

Matsumoto, Tsuyoshi

Suzuki, Hiroyuki

Okazaki, Renji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)78905-2

2,4,6-Trisphenyllithium (TbLi) gave a novel 1,3-silicon rearrangement product above -30 deg C, while the treatment of TbLi with some electrophiles also afforded 1,3-silicon rearrangement products even at -78 deg C probably via single electron transfer mechanism.

Full text of DOI:10.1016/S0040-4039(00)78905-2

Products guided by the article

Product name:C₂₇H₅₉⁽²⁾HSi₆

Cas No:134870-83-0

R&D Labs maybe for 134870-83-0

Xi'an Tizan Tech & Industry Co., Ltd.

Contact:86-18629066522

Address:C3009 TANG FENG INTERNATIONAL PLAZA, NO.18 FENGHUI NAN ROAD, XI'AN HIGH TECH ZONE, 710075 CHINA.
Taixing Joxin Bio-tec Co.,Ltd.

website:http://www.joxbio.com

Contact:86-523-87558858 87612088

Address:No.88, chengdong industrial park
Suzhou Wedo Chemicals Co., Ltd.

Contact:86 512 58100425

Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
Qingdao Kylin Trading Co., Ltd.

Contact:0086-532-68979884/58972912/68972263/65/88171519

Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
Wuxi D-Stone International Co., Ltd.

Contact:+86-510-82740567

Address:21F Hengtong Int'l Centre, 215Zhongshan Road, Wuxi, Jiangsu,China

Relevant to this article

Topochemical photodimerization of (E)-3-benzylidene-4-chromanone derivatives from β-type structures directed by halogen groups

Doi:10.1016/j.tet.2011.09.087
(2011)
Structure-guided evolution of potent and selective CHK1 inhibitors through scaffold morphing

Doi:10.1021/jm2007326
(2011)
Structure, absorption and fluorescence of (bi)thiophene substituted methylidene-pyrrolinones Dedicated to Professor Milo? Nepra? in occasion of his 80th birthday

Doi:10.1016/j.molstruc.2013.03.055
(2013)
A NEW SYNTHESIS OF 3-DEAZATHYMIDINE AND OF A RELATED PHOSPHORAMIDITE SYNTHON

Doi:10.1016/S0040-4020(01)88214-4
(1992)
Enantio- and diastereoselective palladium catalysed arylative and vinylative allene carbocyclisation cascades

Doi:10.1039/c3cc42079e
(2013)
Indazole-based potent and cell-active Mps1 kinase inhibitors: Rational design from pan-kinase inhibitor anthrapyrazolone (SP600125)

Doi:10.1021/jm4000215
(2013)

Article Doi