Unusual 1,3-Rearrangement of Trimethylsilyl Group in the Reaction of 2,4,6-Trisphenyllithium

DOI: 10.1016/S0040-4039(00)78905-2

Source and publish data:

Tetrahedron Letters p. 2049 - 2052 (1991)

Update date:2022-07-30

Topics: Reaction Experimental Trimethylsilyl Phenyllithium

Authors:

Tokitoh, Norihiro

Matsumoto, Tsuyoshi

Suzuki, Hiroyuki

Okazaki, Renji

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Article abstract of DOI:10.1016/S0040-4039(00)78905-2

2,4,6-Trisphenyllithium (TbLi) gave a novel 1,3-silicon rearrangement product above -30 deg C, while the treatment of TbLi with some electrophiles also afforded 1,3-silicon rearrangement products even at -78 deg C probably via single electron transfer mechanism.

Full text of DOI:10.1016/S0040-4039(00)78905-2

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