134875-79-9Relevant academic research and scientific papers
The dienolate aldol reaction of (E)-N-crotonoyl C(4)-isopropyl SuperQuat: asymmetric synthesis of α-vinyl-β-hydroxycarboxylic acid derivatives and conversion to α-ethylidene-β-hydroxyesters (β-substituted Baylis-Hillman products)
Davies, Stephen G.,Elend, Dirk L.,Jones, Simon,Roberts, Paul M.,Savory, Edward D.,Smith, Andrew D.,Thomson, James E.
experimental part, p. 7837 - 7851 (2009/12/09)
The synthesis of α-vinyl-β-hydroxyesters and α-ethylidene-β-hydroxyesters (β-substituted Baylis-Hillman products) via the dienolate aldol reaction of (E)-N-crotonoyl C(4)-isopropyl SuperQuat is described. High levels of syn-diastereoselectivity (up to >98
