134878-50-5

Basic information

• Product Name: 1-Butene, 3-(1,1-dimethylethoxy)-3-methyl-
• CAS NO: 134878-50-5
• Molecular Formula: C9H18O
• Molecular Weight: 142.241
• Mol File: 134878-50-5.mol

Chemical Properties

• CAS DataBase Reference: 1-Butene, 3-(1,1-dimethylethoxy)-3-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Butene, 3-(1,1-dimethylethoxy)-3-methyl-(134878-50-5)
• EPA Substance Registry System: 1-Butene, 3-(1,1-dimethylethoxy)-3-methyl-(134878-50-5)

Safety Data

• Hazardous Substances Data: 134878-50-5(Hazardous Substances Data)

Upstream product

• 507-40-4 tert-butylhypochlorite 
• 115-18-4 2-methyl-3-buten-2-ol 
• 558-17-8 tert-Butyl iodide 
• 2190-48-9 3-chloro-3-methyl-1-butene 
• 75-65-0 tert-butyl alcohol 
• 2154-65-6 1,3,5-triphenylverdazyl 

Relevant articles and documents

Kinetics and mechanism of monomolecular heterolysis of commercial organohalogen compounds: XLIII. Solvent effect on activation parameters of dehydrochlorination of 3-chloro-3-methylbut-1-ene. Correlation analysis of solvation effects

The influence of temperature on the rate of dehydrochlorination of 3-chloro-3-methylbut-1-ene in 17 aprotic and 13 protic solvents, ν = k[C 5H9Cl], was studied by the verdazyl method. In aprotic solvents, the electrophilicity, ionizing power, and cohesion of solvents decrease ΔG ≠ by increasing ΔS ≠. The nucleophilicity and polarizability increase both ΔH ≠ and ΔS ≠ to equal extent and therefore do not affect ΔG ≠. In protic solvents, the solvent nucleophilicity increases ΔH ≠ to a greater extent than ΔS ≠, and the overall effect of the nucleophilic solvation is small and negative.

Kinetics and mechanism of monomolecular heterolysis of commercial organohalogen compounds: XLI. Solvent effect on the rate of 3-methyl-3-chloro-1- butene solvolysis. Correlation analysis of solvation effects and role of solvent nucleophilicity

The kinetics of 3-methyl-3-chloro-1-butene solvolysis at 25°C in MeOH, EtOH, BuOH, i-BuOH, PentOH, 2-PrOH, 2-BuOH, HexOH, OctOH, t-BuOH, t-PentOH, cyclohexanol, and allyl alcohol was studied by the verdazyl method; v = k[C 5H9Cl], SN1 + E1 mechanism. The reaction rate shows a satisfactory correlation with the parameter of the solvent ionizing power E T and is independent of the solvent nucleophilicity. 2005 Pleiades Publishing, Inc.

A New Synthesis of Hindered Unsymmetrical t-Alkyl Ethers

The unusual Williamson reactions of t-butyl and t-pentyl halides with lithium t-alkoxides or with t-alkyl alcohols and amines were carried out at 20-50 deg C.Some of the nucleophilic substitution products were new unsymmetrical ethers: t-butyl t-pentyl ether, t-butyl 1,1-dimethyl-2-propenyl ether, t-butyl 1,1-dimethyl-2-propynyl ether, 1,1-dimethyl-2-propynyl t-pentyl ether, and t-butyl 1-ethyl-1-methyl-2-propynyl ether.

REACTIONS OF α,α-DIMETHYLALLYL ALCOHOL WITH POSITIVE CHLORINATION REAGENTS: SYNTHESIS OF 1-CHLORO-2,3-EPOXY-3-METHYLBUTANE

Various approaches to the synthesis of the title compound, 1-chloro-2,3-epoxy-3-methylbutane, via the chlorination reactions of α,α-dimethylallyl alcohol have been followed.Attempted one-step synthesis of the epoxide from the substrate alcohol with either highly alkaline sodium hypochlorite, or t-butyl hypochlorite in the absence of solvent, gave mediocre yields of epoxide, accompanied by a variety of chlorinated products via mechanistic pathways proposed to involve neighbouring group participation (NGP) of the hydroxyl moiety.Good overall yields of epoxide were obtained in a two step synthesis involving chlorination of the alcohol with chlorine gas in solvent, followed by treatment of the chlorohydrin product with either base or dry silica gel.