134889-90-0Relevant academic research and scientific papers
Activation of Carbon Dioxide: Nickel-Catalyzed Electrochemical Carboxylation if Diynes
Derien, Sylvie,Clinet, Jean-Claude,Dunach, Elisabet,Perichon, Jacques
, p. 2578 - 2588 (2007/10/02)
The simualtaneous activation of carbon dioxide and diynes by electrogenerated LNi(0) complexes (L=bpy, pentamethyldiethylenetriamine: PMDTA) enables the selective incorporation of one molecule of CO2 into the unsaturated systems and the preparative-scale
First Example of Direct Carbon Dioxide Incorporation into 1,3-Diynes: A Highly Regio- and Stereo-selective Nickel-catalysed Electrochemical Reaction
Derien, Sylvie,Clinet, Jean-Claude,Dunach, Elisabet,Perichon, Jacques
, p. 549 - 550 (2007/10/02)
The electrosynthesis of 2-vinylidene-3-yne carboxylic acids from carbon dioxide and substituted 1,3-diynes is catalysed by a nickel-triamine complex and results in a regio- and stereo-selective addition to one triple bond.
