134891-47-7Relevant academic research and scientific papers
Formation and Mechanistic Implication of a Novel Thiaazabicyclooctane Derivative During the Cycloaddition of N-Acetyl Cinnamic Acid Thioamide
Szantay, Csaba,Moldvai, Istvan,Fishwick, Colin W. G.,Hill, D. R.
, p. 2529 - 2532 (1991)
In the course of synthesizing thiopyran 3a, the novel thiaazabicyclooctane 8, a precursor to 3a, has been isolated as a major product.The formation of 8 provides further insight into the mechanism of the cycloaddition involving 1a, which we have previously discussed to be an efficient way of generating usefully functionalised dihydrothiopyrans.The structure of compound 8 was established by detailed NMR investigations.
