13490-71-6

Upstream product

• 13490-70-5 (+/-)-α-tert-butylphenylacetic acid 
• 27854-88-2 (R)-1-(4-pyridinyl)ethanol 
• 88549-56-8 C₂₄H₃₀O₃ 
• 124-38-9 carbon dioxide 
• 1688-17-1 1-chloro-2,2-dimethyl-1-phenylpropane 
• 1207362-44-4 (S)-4-benzyl-3-(3,3-dimethylbutanoyl)-5,5-dimethyloxazolidin-2-one 
• 103-82-2 phenylacetic acid 
• 103-80-0 phenylacetyl chloride 

Downstream Products

• 33124-21-9 (R)-3,3-Dimethyl-2-phenyl-1-butanol 
• 54321-15-2 (S)-3,3-Dimethyl-2-phenyl-1-butanol 
• 26164-17-0 methyl (S)-2-phenyl-3,3-dimethylbutanoate 

Relevant academic research and scientific papers

Stereoselective α-Tertiary Alkylation of N -(Arylacetyl)oxazolidinones

A method has been developed for the α-tertiary alkylation of zirconium enolates of N -(arylacetyl)oxazolidinones. This reaction directly installs an all-carbon quaternary center vicinal to a benzylic tertiary carbon in a highly diastereoselective manner.

Configuration Determination of (R)-(-)-1,1,2-Triphenyl-3,3-dimethylbutane and the Stereochemistry of the Reaction of Benzhydryllithium with (R)-(+)-α-Phenylneopentyl Chloride

A three-step synthesis of optically pure (R)-(-)-1,1,2-triphenyl-3,3-dimethylbutane from (R)-(-)-α-tert-butylphenylacetic acid has been accomplished.The synthesis of α-phenylneopentyl chloroformate from optically pure (R)-(+)-1-phenyl-2,2-dimethyl-1-propa