134903-65-4Relevant academic research and scientific papers
Polyfunctional compounds containing the 4,6-dialkoxy-7-arylthioheptene moiety as synthetically useful intermediates. The course of Lewis acid-induced transformations
Chekmarev, Dmitriy S.,Lazareva, Margarita I.,Zatonsky, Georgy V.,Maskaev, Andrei V.,Caple, Ron,Smit, William
, p. 7957 - 7967 (2007/10/03)
Data on the selectivity of the Lewis acids induced transformations of the title compounds are presented, and the routes leading to formation of products containing either cyclohexane or 1,3-diene units are described.
REACTION SEQUENCE ARYLSULFENYL CHLORIDE + ALKOXYALKENE-I + ALKOXYALKENE-II + ALLYLMAGNESIUM OR BORON DERIVATIVES AS A NEW METHOD FOR THE CONTROLLED SYNTHESIS OF POLYFUNCTIONAL DERIVATIVES
Smolyakova, I. P.,Smit, V. A.,Bubnov, Yu. N.,Shashkov, A. S.
, p. 981 - 987 (2007/10/02)
A new method is proposed for the controlled synthesis of polyfunctional compouds with formation of two new carbon-carbon bonds; the method is based on the following reaction sequence, which can be carried out in a single flask: addition of ArSCl to vinyl ether I, reaction of the resultant adduct with vinyl ether II in the presence of Lewis acid to form a cationic complex, and treatment of the latter with allyl derivatives of boron or magnesium.
Arylsulfenyl chloride mediated coupling of three nucleophilic fragments with the formation of two c= bonds
Smoliakova,Smit,Osinov
, p. 2601 - 2604 (2007/10/02)
The sequence of reactions ArSCl + vinyl ether-I + vinyl ether-II + organomagnesium reagents has been developed as a convergent protocol for assembling polyfunctional cokounds from simple precursors.
