96856-74-5

Upstream product

• 110-87-2 3,4-dihydro-2H-pyran 
• 933-00-6 p-methylbenzenesulfenyl chloride 

Downstream Products

• 95349-81-8 1-(2',2'-dimethoxyethyl)-2-p-tolylthiooxane 
• 120814-13-3 2-(1-formylvinyl)-3-(p-tolylthio)oxane 
• 134903-69-8 (2S,3R)-2-(2-Methoxy-1,1,5-trimethyl-hex-4-enyl)-3-p-tolylsulfanyl-tetrahydro-pyran 
• 134903-72-3 (2S,3R)-2-((R)-2-Methoxy-1,1-dimethyl-3-phenyl-propyl)-3-p-tolylsulfanyl-tetrahydro-pyran 
• 134903-67-6 trans-2-(3'-methoxy-2'-methylhex-5'-en-2'-yl)-3-(p-tolylthio)tetrahydropyran 
• 134903-65-4 threo-2-(1',1',4'-trimethyl-2'-methoxypenten-4'-yl)-3-(p-tolylthio)oxane 
• 134903-65-4 erythro-2-(1',1',4'-trimethyl-2'-methoxypenten-4'-yl)-3-(p-tolylthio)oxane 
• 134903-65-4 trans-2-(3'-methoxy-2',5'-dimethylhex-5'-en-2'-yl)-3-(p-tolylthio)tetrahydropyran 
• 135711-09-0 2-(1',1'-dimethyl-3'-hydroxypenten-4'-yl)-3-(p-tolylthio)oxane 

Relevant academic research and scientific papers

Tandem sequence of ArSCl initiated AdE reactions resulting in formation of two C-C bonds

A one-pot procedure for the sequence of reactions between arylsulfanyl chloride, vinyl ether-I, vinyl ether-II and organomagnesium reagents has been developed for assembling polyfunctional compounds from simple precursors. 2,3-Dihydropyran and various vin

Arylsulfenyl chloride mediated coupling of three nucleophilic fragments with the formation of two c= bonds

The sequence of reactions ArSCl + vinyl ether-I + vinyl ether-II + organomagnesium reagents has been developed as a convergent protocol for assembling polyfunctional cokounds from simple precursors.

REACTION SEQUENCE ARYLSULFENYL CHLORIDE + ALKOXYALKENE-I + ALKOXYALKENE-II + ALLYLMAGNESIUM OR BORON DERIVATIVES AS A NEW METHOD FOR THE CONTROLLED SYNTHESIS OF POLYFUNCTIONAL DERIVATIVES

A new method is proposed for the controlled synthesis of polyfunctional compouds with formation of two new carbon-carbon bonds; the method is based on the following reaction sequence, which can be carried out in a single flask: addition of ArSCl to vinyl ether I, reaction of the resultant adduct with vinyl ether II in the presence of Lewis acid to form a cationic complex, and treatment of the latter with allyl derivatives of boron or magnesium.