1349097-52-4

Upstream product

• 158535-88-7 2,3-Di-O-benzyl-4-O-(tert-butyldimethylsilyl)-D-erythrose 
• 158535-87-6 (2R,3R)-2,3-Bis(benzyloxy)-4-<(tert-butyldimethylsilyl)oxy>-N-methoxy-N-methylbutanamide 
• 158535-86-5 (2R,3R)-2,3-Bis(benzyloxy)-4-hydroxy-N-methoxy-N-methylbutanamide 
• 130412-79-2 (2R,3R)-2,3-bis(benzyloxy)-4-hydroxybutanoic acid 1,4-lactone 
• 100-39-0 benzyl bromide 
• 1349097-36-4 ⁽¹⁾-(RS,E,2S,3R)-N-[2,3-bis(benzyloxy)-4-(tert-butyldimethylsilyloxy)butylidene]-2-methylpropane-1-sulfinamide 
• 106-95-6 allyl bromide 
• 1349097-51-3 (-)-(RS,2R,3S,4R)-3,4-di(benzyloxy)-2-[(R)-1-(methoxymethoxy)allylpyrrolidin-1-yl]-2-methylpropane-2-sulfinamide 
• 1349097-50-2 (-)-(RS,2S,3R,4R,5R)-N-[2,3-dibenzyloxy-1-hydroxy-5-(methoxymethoxy)hept-6-en-4-yl]-2-methylpropane-2-sulfinamide 
• 1349097-48-8 (-)-(RS,2S,3R,4R,5R)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-en-4-yl]-2-methylpropane-2-sulfinamide 
• 1349097-39-7 (-)-(RS,2S,3R,4R,5R)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-(methoxymethoxy)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide 
• 1349097-40-0 (-)-(RS,2S,3R,4R,5R)-N-[1-(tert-butyldimethylsilyloxy)-2,3-dibenzyloxy-5-methoxymethoxy-7-(trimethylsilyl)hept-6-yn-4-yl]-2-methylpropane-2-sulfinamide 

Downstream Products

• 1349097-55-7 (-)-(1S,2R,8R,8aR)-1,2-di(benzyloxy)-8-methoxymethoxy-1,2,3,5,8,8a-hexahydroindolizine 

Relevant academic research and scientific papers

Synthesis of (-)-swainsonine and (-)-8epi-swainsonine by the addition of allenylmetals to chiral α,β-alkoxy sulfinylimines

The asymmetric synthesis of (-)-swainsonine and (-)-8epi-swainsonine is reported through the addition of either the allenylzinc or the allenyl lithio cyanocuprate reagents derived from [3-(methoxymethoxy)prop-1-ynyl] trimethylsilane to enantiopure α,β-dialkoxy N-tert- butanesulfinylimines derived from Derythronolactone.