134960-79-5Relevant academic research and scientific papers
Effect of the nature of the tetrapyrrole macrocycle on the transmetallation of Zn2+ and Cd2+ porphyrins with PdCl2 in dimethylformamide
Chizhova,Mamardashvili
, p. 484 - 488 (2011)
Transmetallation of zinc (Zn2+) and cadmium (Cd2+) complexes of 5,10,15,20-tetraphenylporphin, 5,10,15,20-tetra(4-chlorophenyl) porphyrin, 5,10,15,20-tetra(4-methoxyphenyl)porphyrin, tetrabenzoporphyrin, and octaphenyltetraazaporphyrin with PdCl2 in DMF was studied by spectrophotometry. The influence of the nature of the tetrapyrrole macrocycle on the reactivity of Zn2+ porphyrins toward palladium chloride in boiling DMF was established. Palladium(II) complexes of 5,10,15,20- tetraphenylporphyrin, 5,10,15,20- tetra(4-chlorophenyl)porphyrin, 5,10,15,20-tetra(4-methoxyphenylporphyrin), and tetrabenzoporphyrin were prepared and identified. Pleiades Publishing, Ltd., 2011.
