1349697-01-3

Upstream product

• 501-53-1 benzyl chloroformate 
• 1040384-28-8 N-benzoyl-D-serine methyl ester 
• 1349697-11-5 (4R,5R,6R)-5-(tert-butyldimethylsilyloxy)-4-((tert-butyldimethylsilyloxy)methyl)-2-phenyl-6-vinyl-5,6-dihydro-4H-1,3-oxazine 
• 1029529-47-2 (R)-N-(3,8,8,9,9-pentamethyl-4-oxo-2,7-dioxa-3-aza-8-siladecan-5-yl)benzamide 
• 1029529-45-0 (R)-methyl 2-benzamido-3-(tert-butyldimethylsilyloxy)propanoate 
• 1029529-52-9 N-((2R,3S,E)-1-(tert-butyldimethylsilyloxy)-6-chloro-3-hydroxyhex-4-en-2-yl)benzamide 
• 1029529-50-7 (R,E)-N-(1-(tert-butyldimethylsilyloxy)-6-chloro-3-oxohex-4-en-2-yl)benzamide 

Downstream Products

• 1349697-02-4 (3R,4R,5R)-4-(tert-butyldimethylsilyloxy)-5-((tert-butyldimethylsilyloxy)methyl)pyrrolidin-3-yl benzoate 

Relevant academic research and scientific papers

A concise synthesis of (-)-lentiginosine via an anti,syn-oxazine

A concise and stereocontrolled total synthesis of (-)-lentiginosine, a potent glycosidase inhibitor, has been achieved. Starting from anti,syn-oxazine as a chiral building block, the key features in these strategies are the Wittig reaction and cyclization

Efficient and stereoselective syntheses of DAB-1 and D-fagomine via chiral 1,3-oxazine

The concise, stereocontrolled syntheses of DAB-1 and d-fagomine were achieved utilizing chiral oxazine. The key features in these strategies are the stereoselective intramolecular oxazine formation catalyzed by palladium(0), and pyrrolidine and piperidine formation by catalytic hydrogenation of oxazine.