1029529-47-2

Upstream product

• 1029529-45-0 (R)-methyl 2-benzamido-3-(tert-butyldimethylsilyloxy)propanoate 
• 6638-79-5 N,O-dimethylhydroxylamine*hydrochloride 
• 1040384-28-8 N-benzoyl-D-serine methyl ester 

Downstream Products

• 1029529-50-7 (R,E)-N-(1-(tert-butyldimethylsilyloxy)-6-chloro-3-oxohex-4-en-2-yl)benzamide 
• 1029529-75-6 N-((2R,3R,E)-1-(tert-butyldimethylsilyloxy)-6-chloro-3-hydroxyhex-4-en-2-yl)benzamide 
• 1029529-52-9 N-((2R,3S,E)-1-(tert-butyldimethylsilyloxy)-6-chloro-3-hydroxyhex-4-en-2-yl)benzamide 
• 1349697-08-0 (4R,5R,6S)-5-(benzyloxy)-4-((tert-dimethylsilyloxy)methyl)-2-phenyl-6-vinyl-5,6-dihydro-4H-1,3-oxazine 
• 1349697-07-9 (4R,5R,6R)-5-(benzyloxy)-4-((tert-dimethylsilyloxy)methyl)-2-phenyl-6-vinyl-5,6-dihydro-4H-1,3-oxazine 
• 1349697-10-4 (4R,5R,6S)-4-((tert-butyldimethylsilyloxy)methyl)-5-(methoxymethoxy)-2-phenyl-6-vinyl-5,6-dihydro-4H-1,3-oxazine 
• 1349697-09-1 (4R,5R,6R)-4-((tert-butyldimethylsilyloxy)methyl)-5-(methoxymethoxy)-2-phenyl-6-vinyl-5,6-dihydro-4H-1,3-oxazine 
• 1349697-11-5 (4R,5R,6R)-5-(tert-butyldimethylsilyloxy)-4-((tert-butyldimethylsilyloxy)methyl)-2-phenyl-6-vinyl-5,6-dihydro-4H-1,3-oxazine 
• 1349697-01-3 (3R,4R,5R)-5-(benzyloxycarbonylamino)-4,6-bis(tert-butyldimethylsilyloxy)hex-1-en-3-yl benzoate 
• 1349697-02-4 (3R,4R,5R)-4-(tert-butyldimethylsilyloxy)-5-((tert-butyldimethylsilyloxy)methyl)pyrrolidin-3-yl benzoate 
• 1349697-03-5 2-((4R,5R,6R)-5-(tert-butyldimethylsilyloxy)-4-((tert-butyldimethylsilyloxy)methyl)-2-phenyl-5,6-dihydro-4H-1,3-oxazin-6-yl)ethanol 
• 1349697-13-7 C₂₆H₄₇NO₆SSi₂ 
• 1349697-00-2 C₂₀H₃₂ClNO₃Si 
• 1349697-14-8 C₂₆H₃₆ClNO₃Si 

Relevant academic research and scientific papers

Stereoselective allylation reactions of acyclic and chiral α-amino-β-hydroxy aldehydes 3: Total synthesis of (+)-1-epi-castanospermine

Stereoselective allylation reactions of acyclic, chiral α-amino-β-hydroxy aldehydes containing four contiguous stereocenters were conducted. Allylation mediated by MgBr2?OEt2 afforded the anti-product. A plausible mechanism of the allylation reaction is also described. The resulting allylation product was used for the total synthesis of (+)-1-epi-castanospermine.

Efficient and stereoselective syntheses of DAB-1 and D-fagomine via chiral 1,3-oxazine

The concise, stereocontrolled syntheses of DAB-1 and d-fagomine were achieved utilizing chiral oxazine. The key features in these strategies are the stereoselective intramolecular oxazine formation catalyzed by palladium(0), and pyrrolidine and piperidine formation by catalytic hydrogenation of oxazine.

Stereoselective synthesis of (+)-polyoxamic acid based on the synthesis of chiral oxazine

A concise, stereocontrolled synthesis of (+)-polyoxamic acid was achieved. Starting from trans-oxazoline as a chiral building block, the key step involves diastereoselective oxazine formation catalyzed by palladium(0). The Royal Society of Chemistry.