135039-71-3Relevant academic research and scientific papers
An Unprecedented Intramolecular Migration of Carbon Groups from Aluminum to an Adjacent Vinylic Center and Its Application to the Synthesis of Stereodefined Olefins
Miller, Joseph A.
, p. 998 - 1000 (1989)
Hydroalumination of 1-chloro-1-alkynes by sodium trialkylaluminum hydrides furnishes stereo- and regioselectively the respective (E)-1-chloro-1-alkenylalanates, which, in the presence of NaOMe, undergo a novel 1,2-migration of a carbon group from Al to the adjacent vinylic center to generate a useful synthesis of di- and trisubstituted olefins of defined geometry.
