Journal of Organic Chemistry p. 998 - 1000 (1989)
Update date:2022-07-29
Topics:
Miller, Joseph A.
Hydroalumination of 1-chloro-1-alkynes by sodium trialkylaluminum hydrides furnishes stereo- and regioselectively the respective (E)-1-chloro-1-alkenylalanates, which, in the presence of NaOMe, undergo a novel 1,2-migration of a carbon group from Al to the adjacent vinylic center to generate a useful synthesis of di- and trisubstituted olefins of defined geometry.
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Doi:10.1021/ja108516b
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