135040-07-2Relevant academic research and scientific papers
Selective anodic fluorination of electrophilic alkenes
Dinoiu, Vasile,Kanno, Kazuako,Fukuhara, Tsuyoshi,Yoneda, Norihiko
, p. 753 - 758 (2005)
Anodic fluorination of some electrophilic alkenes (conjugated with electron-withdrawn groups), ethyl cinnamates, RC6H 4CHCHCO2Et (R = H, CH3, CH3O, F and CF3), cinnamonitrile, C6H4CHCHCN, phenyl stryryl ketone, and t-butyl styryl ketone using ammonium fluorides as the fluorine source and supporting electrolyte, in CH2Cl2 as electrolytic solvent yields the expected vicinal difluoro compounds, as mixture of erythro and threo isomers. The anodic fluorination of phenyl 3,5-di-t-butyl-4-hydroxystyryl ketone yields two monofluoro compounds. A possible reaction mechanism is discussed.
