1350430-29-3

Upstream product

• 1160297-40-4 1,3-dipropylamineimidazolium bromide 
• 1384631-95-1 (R,R)-N-(3,5-di-tert-butylsalicylidene)-N′-(3-tert-butyl-5-chloromethyl-salicylidene)-1,2-cyclohexanediamine 
• 37942-07-7 3,5-di-tert-butyl-2-hydroxybenzaldehyde 
• 20439-47-8 (1R,2R)-1,2-diaminocyclohexane 
• 183017-88-1 3-tert-butyl-5-(chloromethyl)-2-hydroxybenzaldehyde 

Relevant academic research and scientific papers

Recyclable ionic liquid-bridged chiral dimeric salen Mn(III) complexes for oxidative kinetic resolution of racemic secondary alcohols

Novel chiral dimeric salen Mn(III) complexes bridged with N,N-dialkylimidazolium ionic liquids (ILs) at the C-5 position of the salicylaldehyde moieties were designed and synthesized. The ILs-bridged complexes presented excellent enantioselectivity and catalytic activity in the oxidative kinetic resolution of α-methyl benzyl alcohol, using diacetoxyiodobenzene as oxidant. The complexes combined the high catalytic efficiency of the active centers and the special solubility of the ILs, thus exhibiting notable efficacy of oxidative kinetic resolution and facile recovery from the reaction system by changing the solvent.