135056-52-9Relevant academic research and scientific papers
A peculiar reaction of aminoallenes with aromatic and heteroaromatic aldehydes
Nijs,Verkruijsse,Harder,Van der Kerk,Brandsma
, p. 653 - 656 (1991)
Addition of the allenic amine H2C = C = CHNMe2 and the corresponding N-morpholinoallene to a solution of an aromatic or heteroaromatic aldehyde, RCH = O, and lithium bromide in tetrahydrofuran followed by treatment of the reaction mixture with a small amount of acetic acid at elevated temperatures affords the aldehydes RCH = C (CH2NR'2) CH = O (NR'2 = NMe2 or morpholino) in reasonable yields.
