1350623-73-2Relevant articles and documents
Stereocontrolled total synthesis of polygalolide A
Yamada, Hitomi,Adachi, Masaatsu,Isobe, Minoru,Nishikawa, Toshio
, p. 1428 - 1435 (2013/07/26)
The total synthesis of polygalolide A, a secondary metabolite that was isolated from a Chinese medicinal plant, is reported. A key issue in this synthesis was construction of an oxabicyclo[3.2.1] skeleton, which was solved by the development of an intramo
Total synthesis of polygalolide A
Adachi, Masaatsu,Yamada, Hitomi,Isobe, Minoru,Nishikawa, Toshio
, p. 6532 - 6535 (2012/02/15)
The total synthesis of polygalolide A was accomplished through intramolecular C-glycosylation of glucal modified with siloxyfuran. The siloxyfuran group and siloxy substituent at the C-3 position played crucial roles in allowing direct access to the highl