13507-10-3

Basic information

• Product Name: 2-Hydroxy-1,3,2-dioxaphosphorinane 2-oxide
• Synonyms: 2-Hydroxy-1,3,2-dioxaphosphorinane 2-oxide;Cyclic trimethylene phesphate;Trimethylene phosphate
• CAS NO: 13507-10-3
• Molecular Formula: C3H7O4P
• Molecular Weight: 138.06
• Mol File: 13507-10-3.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Hydroxy-1,3,2-dioxaphosphorinane 2-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hydroxy-1,3,2-dioxaphosphorinane 2-oxide(13507-10-3)
• EPA Substance Registry System: 2-Hydroxy-1,3,2-dioxaphosphorinane 2-oxide(13507-10-3)

Safety Data

• Hazardous Substances Data: 13507-10-3(Hazardous Substances Data)

Upstream product

• 31121-06-9 2-methoxy-[1,3,2]dioxaphosphinane 
• 1184-78-7 trimethylamine-N-oxide 
• 504-63-2 trimethyleneglycol 
• 86119-84-8 phosphoric acid 
• 627-30-5 1-chloro-3-hydroxypropane 
• 64821-66-5 2-Benzyloxy-[1,3,2]dioxaphosphinane 2-oxide 
• 85437-93-0 3-(2-Oxo-2λ⁵-[1,3,2]dioxaphosphinan-2-yloxy)-butan-2-one 
• 52066-54-3 dimethyl-[2-(2-oxo-2λ⁵-[1,3,2]dioxaphosphinan-2-yloxy)-ethyl]-amine 
• 697-39-2 2-ethoxy-[1,3,2]dioxaphosphinane 2-oxide 
• 100974-47-8 phosphoric acid-(3-hydroxy-propyl ester)-diphenyl ester 
• 13507-42-1 phosphoric acid mono-(3-hydroxy-propyl) ester 

Downstream Products

• 13507-42-1 phosphoric acid mono-(3-hydroxy-propyl) ester 

Relevant articles and documents

Controlled/living ring-opening polymerization of ε-caprolactone catalyzed by phosphoric acid

The bulk ring-opening polymerization (ROP) of ε-caprolactone (ε-CL) by various phosphoric acids using phenylmethanol as the initiator was conducted. 1,1'-bi-2-Naphthol (BINOL)-based phosphoric acid was found to be an effective organocatalyst for ROP leading to polyesters at 90°C. The overall conversion to poly(ε-caprolactone) was more than 96% and poly(ε-caprolactone) with Mw of 8400 and polydispersity index of 1.13 was obtained. 1H NMR spectra of oligomers demonstrated the quantitative incorporation of the protic initiator in the polymer chains and showed that transesterification reactions did not occur to a significant extent. The controlled polymerization was indicated by the linear relationships between the number- average molar mass and monomer conversion or monomer-to-initiator ratio. In addition, the present protocol provided an easy-to-handle, inexpensive and environmentally benign entry for the synthesis of biodegradable materials as well as polyesters for biomedical applications. Science China Press and Springer-Verlag Berlin Heidelberg 2012.

Cyclic glycerophosphates and analogs thereof

Cyclic glycerophosphates as well as some analogs thereof (CGs) are shown to increase phosphorylation of intracellular proteins in various cells. Such activity is not found with linear α or β glycerophosphates. The phosphorylating activity of the CGs rende

A Facile Synthesis of Cyclic Phosphodiesters

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