1350846-05-7Relevant academic research and scientific papers
MnCO3-Catalyzed Transesterification of Alcohols with Dimethyl Carbonate Under Mild Conditions
Bi, Xiuru,Yao, Nan,Meng, Xu,Gou, Mingxia,Zhao, Peiqing
, p. 454 - 462 (2021)
Abstract: Dimethyl carbonate (DMC) is a valuable green reagent with versatile and tunable chemical reactivity and can be used as a raw material for transesterification of alcohols. Herein, MnCO3 was found to be an efficient heterogeneous cataly
Palladium-catalyzed benzylic substitution of benzyl carbonates with phosphorus nucleophiles
Makida, Yusuke,Usui, Kazumi,Ueno, Satoshi,Kuwano, Ryoichi
supporting information, p. 1814 - 1817 (2017/11/23)
A wide range of benzyl carbonates reacted with dimethyl phosphonate or diphenylphosphine oxide in the presence of the palladium catalyst, [Pd(η3-allyl)Cl]2DPEphos, to give dimethyl benzylphosphonates and benzyldiphenylphosphine oxides in high yields. The catalytic phosphonylation was applied to the one-pot synthesis of alkenes from the benzyl esters.
Palladium-catalyzed C3-benzylation of indoles
Zhu, Ye,Rawal, Viresh H.
supporting information; experimental part, p. 111 - 114 (2012/03/07)
A general method for regioselective C3-benzylation of indoles has been developed. Various 3-substituted indoles and benzyl methyl carbonates with different electronic properties react under mild conditions to afford a diverse range of 3-benzylindolenine products in good yields.
