13509-32-5Relevant academic research and scientific papers
Method for preparing trithiomethyl carbonate phenyl ester compound with hypoglycemic effect
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Paragraph 0043-0048, (2020/10/05)
The invention discloses a method for preparing a trithiomethyl carbonate phenyl ester compound with a hypoglycemic effect. The preparation method comprises the steps that a thiophenol compound shown in the formula (I), carbon disulfide shown in the formula (II) and methyl iodide shown in the formula (III) react in benzene serving as a medium with sodium tert-butoxide serving as a catalyst to prepare a target product, and the product is subjected to aftertreatment to prepare the trithiomethyl carbonate phenyl ester compound. The method is good in yield; the catalyst is efficient and meets the green and environment-friendly requirements; the catalytic system is wide in adaptability and suitable for large-scale industrial intermediate production. In the reaction formula, R is one of the following groups: hydrogen, tert-butyl, chlorine, bromine, trifluoromethyl and pyridyl.
Triethylamine-catalyzed one-pot synthesis of trithiocarbonates from carbon disulfide, thiols, and alkyl halides in water
Movassagh, Barahman,Soleiman-Beigi, Mohammad
experimental part, p. 927 - 930 (2009/09/06)
Symmetrical and unsymmetrical trithiocarbonates were prepared by a simple and efficient one-pot reaction of thiols, carbon disulfide, and alkyl halides in the presence of triethylamine in water at room temperature.
Organic reactions in ionic liquids: Synthesis of alkyl aryl trithiocarbonates by the S-arylation of potassium carbonotrithioates with diaryliodonium salts
Wang, Feng-Yan,Chen, Zhen-Chu,Zheng, Qin-Guo
, p. 810 - 811 (2007/10/03)
Various alkyl aryl trithiocarbonates were readily prepared in good yields by the S-arylation of potassium carbonotrithioates with diaryliodonium salts in the room-temperature ionic liquid, 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim]BF4). The ionic liquid can be recycled and reused.
ONE-POT SYNTHESIS OF ALKYL ARYL TRITHIOCARBONATES FROM BENZENETHIOLS, ALKYL HALIDES, AND CARBON DISULFIDE WITH A PHASE-TRANSFER CATALYST.
Sugawara,Shirahata,Sato,Sato
, p. 3353 - 3354 (2007/10/02)
Various alkyl aryl trithiocarbonates may readily be synthesized in good yield at low temperatures such as 20 degree C by allowing trioctylmethylammonium chloride (phase-transfer catalyst) to catalyze reaction of benzenethiols and alkyl halides with carbon disulfide.
