135103-74-1Relevant articles and documents
The 2,4,6-tris(trifluoromethyl)phenyl group: Methyl and vinyl ketones and related chemistry
Filler, Robert,Kong, Zhengrong,Zhang, Zhaoxu,Sinha, Arun Kr.,Li, Xiaofang
, p. 71 - 75 (2007/10/03)
2,4,6-Tris(trifluoromethyl)phenyllithium (1) reacts with acetaldehyde and acrolein to give the corresponding alcohols 5 and 8. Oxidation of the alcohols with the CrO3-pyridine complex affords the acetophenone 3 and the vinyl ketone 7 respectively. The reactions of 1 with trifluoroacetic anhydride and trimethylsilyl trifluoroacetate give low to moderate yields of the trifluoroacetophenone 6.