135131-61-2

Upstream product

• 142543-92-8 1L-1,2-O-isopropylidene-5,6-di-O-methyl-chiro-inositol 
• 98-88-4 benzoyl chloride 
• 58769-23-6 1L-3,4,:5,6-di-O-isopropylidene-2-O-methyl-chiro-inositol 
• 19647-44-0 1L-1,2:3,4-di-O-isopropylidene-5,6-di-O-methyl-chiro-inositol 

Downstream Products

• 135131-62-3 1L-3-O-benzoyl-1,2-O-isopropylidene-5,6-di-O-methyl-4-O-methylsulfonyl-chiro-inositol 
• 135131-68-9 (2E)-(1R,3S,4S,5S)-2-cyanomethylene-4,5-dimethoxy-1-(p-methoxybenzoyloxy)-3-(tetrahydropyran-2-yloxy)cyclohexane 
• 135267-05-9 (2Z)-(1R,3S,4S,5S)-2-cyanomethylene-4,5-dimethoxy-1-(p-methoxybenzoyloxy)-3-(tetrahydropyran-2-yloxy)cyclohexane 
• 51385-17-2 simmondsin penta-O-acetate 
• 142543-95-1 1D-(1,2,5/3,4)-4-O-benzoyl-5-O-(p-methoxybenzyl)-1,2-di-O-methyl-3-O-(tetrahydropyran-2-yl)cyclohexanepentaol 
• 135131-65-6 1D-(1,2,5/3,4)-4-O-benzoyl-5-O-(p-methoxybenzyl)-1,2-di-O-methylcyclohexanepentaol 
• 135131-69-0 (2E)-(1R,3S,4S,5S)-3-acetoxy-2-cyanomethylene-4,5-dimethoxy-1-(p-methoxybenzoyloxy)cyclohexane 
• 51771-52-9 (7Z)-(1R,3S,4R,5S)-2-(cyanomethylene)-3-hydroxy-4,5-dimethoxycyclohexyl β-D-glucopyranoside 
• 135131-67-8 2D-(2/3,4,6)-6-O-(p-methoxybenzyl)-3,4-di-O-methyl-2-O-(tetrahydropyran-2-yl)-2,3,4,6-tetrahydroxycyclohexanone 
• 135131-66-7 1D-(1,2,5/3,4)-5-O-(p-methoxybenzyl)-1,2-di-O-methyl-3-O-(tetrahydropyran-2-yl)cyclohexanepentaol 
• 142543-96-2 (2Z)-(1R,3S,4S,5S)-2-cyanomethylene-3-hydroxy-4,5-dimethoxy-1-(p-methoxybenzoyloxy)cyclohexane 
• 135131-64-5 1D-(1,2,5/3,4)-3,4-O-isopropylidene-5-O-(p-methoxybenzyl)-1,2-di-O-methylcyclohexanepentaol 
• 135131-70-3 (2E)-(1R,3S,4S,5S)-3-acetoxy-2-cyanomethylene-1-hydroxy-4,5-dimethoxycyclohexane 
• 142543-94-0 1D-(1,2,5/3,4)-5-O-(p-methoxybenzyl)-1,2-di-O-methylcyclohexanepentaol 

Relevant academic research and scientific papers

Synthesis and Absolute Configuration of the Naturally Occurring Cyano Glucoside Simmondsin

The synthesis of the naturally occurring cyano glucoside simmondsin, 1, is reported.An optically active cyclitol, L-quebrachitol 2, was stereoselectively converted into the aglycone 19, which was condensed with D-glucose, follwed by deprotection to provid

Total Synthesis of Simmondsin

The first total synthesis of the naturally occuring cyanoglucoside, simmondsin 1, starting from L-quebrachitol and D-glucose, is described, revealing the absolute configuration of this compound.