1351364-82-3Relevant academic research and scientific papers
Manganese(III)-mediated radical cyclisations for the (Z)-selective synthesis of exo-alkylidene pyrrolidinones and pyrrolidines
Keane, Harriet A.,Hess, Wilfried,Burton, Jonathan W.
, p. 6496 - 6498 (2012/08/08)
The cyclisation of alkynyl amido- and amino-malonates in the presence of manganese(iii) acetate gives exo-alkylidene pyrrolidinones and pyrrolidines with a preference for the (Z)-alkene product isomer.
A zinc(II) catalyst system for the conia-ene reaction of alkynyl-aminomalonates applicable to 5-endo-dig reactions
Hess, Wilfried,Burton, Jonathan W.
supporting information; experimental part, p. 2966 - 2970 (2012/01/03)
The zinc(II)-catalyzed 5-exo-dig (Conia-ene) and 5-endo-dig cyclizations of a range of alkynyl-α-aminomalonates give rise to nitrogen heterocycles with good efficiency. The reaction allows the synthesis of a broad range of synthetically useful building blocks. Copyright
