135145-16-3

Upstream product

• 118834-40-5 o-bromophenylmagnesium bromide 
• 1517-82-4 (-)-menthyl p-toluenesulfinate 
• 15861-49-1 1-bromo-2-(4-methylphenylsulfanyl)benzene 
• 583-55-1 1-Bromo-2-iodobenzene 
• 98147-48-9 2-isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate 
• 106-45-6 para-thiocresol 
• 94718-79-3 o-bromoaniline hydrochloride 

Downstream Products

• 135145-22-1 1-[3-Bromo-2-(toluene-4-sulfinyl)-phenyl]-ethanol 
• 30506-35-5 butyl(p-tolyl)sulfoxide 
• 135145-18-5 2-(1-Hydroxyethyl)phenyl p-tolyl sulfoxide 

Relevant academic research and scientific papers

Synthesis of Diverse o-Arylthio-Substituted Diaryl Ethers by Direct Oxythiolation of Arynes with Diaryl Sulfoxides Involving Migratory O-Arylation

A diverse range of o-arylthio-substituted diaryl ethers has been synthesized by direct oxythiolation of arynes with diaryl sulfoxides that involves the formation of the C-O and C-S bonds followed by migratory O-arylation.

Palladium-catalyzed intramolecular direct arylation of 2-bromo-diaryl sulfoxides via C-H bond activation

Efficient access to dibenzothiophene-S-oxides from differently substituted 2-bromo-diarylsulfinyl moieties using ligandless Pd(OAc)2 as the catalyst and KOAc as the base in dimethylacetamide at 130 C is reported. Various dibenzothiophene-S-oxid

Preparation of optically active ortho-chloro- and ortho-bromophenyl sulfoxides

The preparation of the diastereomerically pure menthyl (S)-2-chloro- and (S)-2-bromophenyl sulfinates by esterification of the corresponding sulfinic acids with (1R,2S,5R)-(-)-menthol and recrystallization/epimerization is reported. The two sulfinates have been converted into enantiomerically pure aryl, vinyl and alkyl sulfoxides by reaction with organomagnesium reagents. These sulfoxides are useful chiral auxiliaries to control the stereochemical outcome of radical reactions.