135145-84-5

Basic information

• Product Name: 1-C-(4-methoxy)phenyl-3,4,6-tri-O-(triisopropylsilyl)-D-glucal
• Synonyms: 1-C-(4-methoxy)phenyl-3,4,6-tri-O-(triisopropylsilyl)-D-glucal
• CAS NO: 135145-84-5
• Molecular Weight: 721.297
• Mol File: 135145-84-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-C-(4-methoxy)phenyl-3,4,6-tri-O-(triisopropylsilyl)-D-glucal(CAS DataBase Reference)
• NIST Chemistry Reference: 1-C-(4-methoxy)phenyl-3,4,6-tri-O-(triisopropylsilyl)-D-glucal(135145-84-5)
• EPA Substance Registry System: 1-C-(4-methoxy)phenyl-3,4,6-tri-O-(triisopropylsilyl)-D-glucal(135145-84-5)

Safety Data

• Hazardous Substances Data: 135145-84-5(Hazardous Substances Data)

Upstream product

• 5720-07-0 4-methoxyphenylboronic acid 
• 135145-81-2 3,4,6-tri-O-triisopropylsilyl-1-iodo-D-glucal 
• 93296-09-4 4-methoxyphenylzinc chloride 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 696-62-8 para-iodoanisole 
• 131216-78-9 1,5-anhydro-2-desoxy-3,4,6-tri-O-triisopropylsilyl-D-arabino-hex-1-enitol 
• 131216-80-3 1,5-anhydro-2-desoxy-3,4,6-tri-O-triisopropylsilyl-1-(tri-n-butyl-stannyl)-D-arabino-hex-1-enitol 

Relevant articles and documents

Palladium-catalyzed cross-coupling reactions between dihydropyranylindium reagents and aryl halides. Synthesis of C-aryl glycals

(Matrix presented) Palladium(0)-catalyzed cross-coupling reactions between tris(dihydropyranyl)indium 1 and aryl halides 2 have been investigated. Aryl iodides and electron-deficient aryl bromides couple efficiently with the in situ-generated indium reage

Preparation of C-Aryl Glucals via the Palladium-Catalyzed Coupling of Metalated Aromatics with 1-Iodo-3,4,6-tri-O-(triisopropylsilyl)-D-glucal

The preparation of the novel iodo glucal 5 from 3,4,6-tri-O-(triisopropylsilyl)-D-glucal (4), via a two-step procedure involving C1 stannylation and subsequent tin-iodine exchange, is described.The palladium-catalyzed coupling of 5 with a variety of metal