135154-77-7Relevant academic research and scientific papers
MECHANISM OF NUCLEOPHILIC SUBSTITUTION IN O,O-DIMETHYL-O-(4-NITROPHENYL)THIOPHOSPHATE IN MICELLAR SOLUTIONS OF 2-HYDROXYETHYLDIMETHYLOCTADECYLAMMONIUM BROMIDE
Tishkova, E. P.,Fedorov, S. B.,Kudryavtseva, L. A.,Bel'skii, V. E.,Ismaev, I. E.,Ivanov, B. E.
, p. 800 - 803 (1991)
The mechanism of nucleophilic substitution in O,O-dimethyl-O-(4-nitrophenyl)-thiophosphate (DNTP) has been studied in alkaline micellar solutions of cationic 2-hydroxyethyl surfactant which displays nucleophilic properties on account of dissociation of the 2-hydroxyethyl group.Further transformation of the intermediate product formed can take place by regeneration of the initial nucleophilic form of the surfactant, or by formation of a new zwitterion form of phosphorylated surfactant.
