Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 800 - 803 (1991)
Update date:2022-08-15
Topics:
Tishkova, E. P.
Fedorov, S. B.
Kudryavtseva, L. A.
Bel'skii, V. E.
Ismaev, I. E.
Ivanov, B. E.
The mechanism of nucleophilic substitution in O,O-dimethyl-O-(4-nitrophenyl)-thiophosphate (DNTP) has been studied in alkaline micellar solutions of cationic 2-hydroxyethyl surfactant which displays nucleophilic properties on account of dissociation of the 2-hydroxyethyl group.Further transformation of the intermediate product formed can take place by regeneration of the initial nucleophilic form of the surfactant, or by formation of a new zwitterion form of phosphorylated surfactant.
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