135186-58-2

Upstream product

• 68241-78-1 6-bromo-1,4-dioxa-spiro[4.4]non-6-ene 
• 135186-48-0 (2α,3β)-1,1-ethylenedioxy-3-(5-benzylthio-2-furyl)-2-(3-oxopropyl)cyclopentane 
• 135186-49-1 (2α,3β)-3-(5-benzylthio-2-furyl)-2-(prop-2-enyl)cyclopentanone 
• 135186-49-1 2-Allyl-3-(5-benzylsulfanyl-furan-2-yl)-cyclopentanone 
• 132948-12-0 2-allylcyclopent-2-enone ethylene ketal 
• 51557-85-8 2-allyl-2-cyclopenten-1-one 
• 13129-40-3 2-(benzylthio)furan 
• 135186-57-1 (2α,3β)-1,1-ethylenedioxy-3-(5-benzylthio-2-furyl)-2-(3-hydroxy-5-methoxycarbonylpent-4-ynyl)cyclopentane 

Downstream Products

• 135186-47-9 (2α,3β)-1,1-ethylenedioxy-3-(5-benzylthio-2-furyl)-2-<(4Z)-3-oxo-5-methoxycarbonylpent-4-enyl>cyclopentane 
• 135186-52-6 (2α,6β,10β,11α)-12-benzylthio-5,5-ethylenedioxy-11-methoxycarbonyl-15-oxatetracyclo<10.2.1.0^3,12.0^7,11>pentadecan-9-one 
• 135186-52-6 (2α,6β,10α,11α)-12-benzylthio-5,5-ethylenedioxy-11-methoxycarbonyl-15-oxatetracyclo<10.2.1.0^3,12.0^7,11>pentadecan-9-one 
• 135186-54-8 C₂₅H₂₈O₆S 

Relevant academic research and scientific papers

Synthetic approaches towards phorbols via the ultra-high-pressure mediated intramolecular Diels-Alder reaction of furans (IMDAF): Effect of furan substitution

Tricyclic structures having the functionality and stereochemistry inherent in phorbol and its analogues may be rapidly constructed by an ultra-high pressure IMDAF reaction. The nature of the 2-thioether substituent on the furan diene is critical for the s

Synthetic Approaches to Phorbols via the Intramolecular Diels-Alder Reactions of Furans (IMDAF): Oxygen Bridge Cleavage and High Stereocontrol during Cycloaddition using α'-Benzylthio Substituted Furan Substrates

High pressure mediated IMDAF of the α'-benzylthiofuran substrate 1 results in efficient and highly stereoselective cycloaddition; subsequent epimerisation of the cycloadduct 6 is regiospecific and the oxygen bridge may be opened by elimination or hydrolys