1352121-40-4Relevant academic research and scientific papers
TBHP-mediated oxidative thiolation of an sp3 C-H bond adjacent to a nitrogen atom in an amide
Tang, Ri-Yuan,Xie, Ye-Xiang,Xie, Yi-Li,Xiang, Jian-Nan,Li, Jin-Heng
, p. 12867 - 12869 (2011)
The first example of molecular sieve-promoted TBHP-mediated direct oxidative thiolation of an sp3 C-H bond adjacent to a nitrogen atom with disulfides under metal-free conditions, which allows for preparation of numerous S,N-containing compounds, is presented. Moreover, diverse benzothiazoles and a fipronil analog can be synthesized through this strategy.
