13524-10-2Relevant academic research and scientific papers
Strictly "pair"-selective and economical synthesis of conjugated diynes via Pd-catalyzed reaction of terminal alkynes with 1,1-dichloroethylene, elimination with LDA, and subsequent transformations
Qian, Mingxing,Negishi, Ei-Ichi
, p. 412 - 417 (2003)
Various unsymmetrically substituted conjugated diynes can be synthesized in a completely "pair"-selective manner via Pd-catalyzed reaction of terminal alkynes with 1,1-dichloroethylene in the presence of Pd(PPh3)4 followed by elimina
SELECTIVE PALLADIUM-CATALYSED SUBSTITUTION OF 1,1-DICHLOROETHYLENE
Ratovelomanana, V.,Hammoud, A.,Linstrumelle, G.
, p. 1649 - 1650 (2007/10/02)
The palladium-catalysed reaction of 1,1-dichloroethylene with acetylenes and vinylalanes affords selectively 2-chloro-1-en-3-ynes and 2-chloro-1,3-dienes in good yields.
