135277-73-5Relevant articles and documents
Generation of Cation Radicals from Allylic Sulfides and Their Reactions with Silyl Enol Ethers by the Use of Cerium(IV) Ammonium Nitrate
Narasaka, Koichi,Okauchi, Tatsuo
, p. 515 - 518 (2007/10/02)
Allyl sulfides react with silyl enol ether, siloxy diene and siloxy enyne by the oxidation with cerium(IV) ammonium nitrate to give α-phenylthio-γ,δ-unsaturated ketones through the nucleophilic addition of silyl enol ethers to the sulfur cation radicals and the successive -sigmatropic rearrangement.