702-00-1

Basic information

• Product Name: METHALLYLPHENYL SULFIDE
• Synonyms: METHALLYLPHENYL SULFIDE
• CAS NO: 702-00-1
• Molecular Formula: C₁₀H₁₂S
• Molecular Weight: 294.45368
• Mol File: 702-00-1.mol
• Article Data: 22

Chemical Properties

• Boiling Point: 227.9°Cat760mmHg
• Flash Point: 90.3°C
• Appearance: /
• Density: 0.99g/cm³
• Vapor Pressure: 0.114mmHg at 25°C
• Refractive Index: 1.553
• CAS DataBase Reference: METHALLYLPHENYL SULFIDE(CAS DataBase Reference)
• NIST Chemistry Reference: METHALLYLPHENYL SULFIDE(702-00-1)
• EPA Substance Registry System: METHALLYLPHENYL SULFIDE(702-00-1)

Safety Data

• Hazardous Substances Data: 702-00-1(Hazardous Substances Data)

Usage

General Description

Methallylphenyl sulfide is a chemical compound with the formula C10H12S. It is a colorless to pale yellow liquid with a garlic-like odor, and is used as a flavoring agent in the food industry. Methallylphenyl sulfide is also found in garlic, onions, and other Allium species. It is known to exhibit antioxidant and antimicrobial properties, and has been studied for its potential use in food preservation and as a natural alternative to synthetic antioxidants and preservatives. Additionally, it has been investigated for its potential health benefits, including its role in reducing the risk of cardiovascular diseases and cancer. Overall, methallylphenyl sulfide is a versatile compound with potential applications in the food industry and health sciences.

InChI:InChI=1/C10H12S/c1-9(2)8-11-10-6-4-3-5-7-10/h3-7H,1,8H2,2H3

Upstream product

• 43161-07-5 ((2-methylallyl)sulfinyl)benzene 
• 108-24-7 acetic anhydride 
• 108-98-5 thiophenol 
• 563-47-3 3-Chloro-2-methylpropene 
• 63996-66-7 2-methyl-2-(phenylthio)propanal 
• 126742-27-6 2-methyl-2-(chloromethyl)thiirane 
• 591-51-5 phenyllithium 
• 1458-98-6 2-methyl-3-bromo-1-propene 
• 882-33-7 diphenyldisulfane 
• 96947-44-3 (2R)-2-methyl-1-(phenylsulfanyl)-3-(tetrahydropyran-2-yloxy)propane 
• 101212-35-5 (2S,4R,5S)-3-(3-phenylthiomethyl-1-oxopropyl)-5-phenyl-oxazolidin-2-one 
• 112995-95-6 (R)-(-)-2-methyl-3-phenylthiopropyl toluene-p-sulphonate 
• 101212-36-6 (R)-(-)-2-methyl-3-(phenylthio)propan-1-ol 
• 51849-22-0 iodomethyl phenyl sulfide 

Downstream Products

• 134706-36-8 (+/-)-4-Methyl-3-phenylthio-4-penten-1-ol 
• 139115-22-3 2-methyl-3-phenylthio-1,6-heptadiene 
• 872978-72-8 8-(phenylsulfanyl)octa-1,6-diene 
• 139115-21-2 2-methyl-3-phenylthio-5-isopropenyl-1,8-nonadiene 
• 135277-72-4 6-Methyl-4-phenylsulfanyl-hepta-1,6-dien-3-one 
• 135277-73-5 2-Methyl-4-phenylsulfanyl-undec-1-en-6-yn-5-one 
• 43161-07-5 ((2-methylallyl)sulfinyl)benzene 
• 49639-05-6 1-(phenylsulfonyl)-2-methyl-2-propene 
• 76126-89-1 3-methyl-1-phenyl-2-(phenylthio)but-3-en-1-ol 
• 76120-57-5 (Z)-3-methyl-1-phenyl-4-(phenylthio)but-3-en-1-ol 
• 76120-56-4 (E)-3-methyl-1-phenyl-4-(phenylthio)but-3-en-1-ol 
• 128815-20-3 ethyl 1-(2-methyl-2-propenyl)-2-oxocyclohexanecarboxylate 
• 58468-95-4 (1,2-dimethyl-allylsulfanyl)-benzene 
• 23092-23-1 3-methyl-1-phenylbut-3-en-1-ol 

Relevant articles and documents

Yb(iii)-catalysedsyn-thioallylation of ynamides

Reported herein is asyn-thioallylation of ynamides incorporating a sulfide moiety at the α-position and an allyl group at the β-position of the ynamide. The transformation is successful under ytterbium(iii)-catalysis, providing access to highly substituted thioamino-skipped-dienes with broad substrate scope. Thus, tetrasubstituted olefins (with four different functional groups: amide, phenyl, thioaryl/alkyl, and allyl on the carbon centers) are made in a single step from readily accessible ynamides, preserving complete atom economy. The reaction can be extended to the synthesis of selenoamino dienes by ynamidesyn-selenoallylation. DFT studies and control experiments provide insight into the reaction mechanism.

Expanding the horizon of intermolecular trapping of in situ generated α-oxo gold carbenes: Efficient oxidative union of allylic sulfides and terminal alkynes via C-C bond formation

With a new P,S-bidentate phosphine as the ligand to gold(i), the α-oxo gold carbenes generated in situ via gold-catalyzed intermolecular oxidation of terminal alkynes were effectively trapped by various allylic sulfides, resulting in the formation of α-aryl(alkyl)thio-γ,δ- unsaturated ketones upon facile [2,3]sigmatropic rearrangements. This journal is the Partner Organisations 2014.

Catalytic activation of diazo compounds using electron-rich, defined iron complexes for carbene-transfer reactions

Carbene transfer: The electron-rich iron complex Bu4N[Fe(CO) 3(NO)] efficiently catalyzes different carbene-transfer reactions. Various diazo compounds can be used. The high stability of the employed iron complexes is demonstrated by the generation of the diazo reagent in situ and a sequential iron-catalyzed allylic sulfenylation/Doyle-Kirmse reaction. Copyright