1352840-99-3Relevant academic research and scientific papers
Pd-catalyzed selective hydrosilylation of aryl ketones and aldehydes
Chouthaiwale, Pandurang V.,Rawat, Varun,Sudalai, Arumugam
, p. 148 - 150 (2012)
Pd salts in combination with triethylsilane as hydride source and DMF as solvent has been found to be excellent catalytic combination that selectively reduces aryl ketones and aldehydes under mild conditions to afford triethylsilyloxy compounds in excellent yields. Product selectivity to the respective benzyl alcohols can however be achieved when the reaction was performed in DMF/H2O (4:1) as solvent system.
Iridacycles as Catalysts for the Autotandem Conversion of Nitriles into Amines by Hydrosilylation: Experimental Investigation and Scope
Hamdaoui, Mustapha,Desrousseaux, Camille,Habbita, Houda,Djukic, Jean-Pierre
supporting information, p. 4864 - 4882 (2018/02/07)
The set of iridacycles [{C,N}Cp?IrIII-Cl] ({C,N} = benzo[h]quinoline, dibenzo[f,h]quinoline) containing the (pentamethylcyclopentadienyl)iridium(III) unit were synthesized and derivatized into cations [{C,N}Cp?Ir-NCMe]+ associated wi
Tandem deuteration/hydrosilylation reactions catalyzed by a rhodium carbene complex under solvent-free conditions
Egbert, Jonathan D.,Nolan, Steven P.
supporting information; experimental part, p. 2794 - 2796 (2012/04/23)
The complex [Rh(ItBu)2HCl] has been shown to be an active catalyst in the hydrosilylation of carbonyl and imine complexes. This reactivity, combined with the previously reported H/D exchange catalyzed by these complexes allows for a
