1352916-63-2Relevant academic research and scientific papers
Asymmetric total synthesis of the epoxykinamycin FL-120 B′
Scully, Stephen S.,Porco Jr., John A.
, p. 9722 - 9726 (2011/12/05)
Turn up the heat: The synthesis of the title compound was achieved and a route to epoxide-containing diazobenzofluorenes, which could potentially serve as monomers to the dimeric lomaiviticins, was established. Key steps to construct the FL-120B′ core structure include Sharpless asymmetric epoxidation, Stille coupling, and intramolecular Friedel-Crafts acylation of atropisomeric carboxylic acids at elevated temperatures. Copyright
