1353040-02-4Relevant academic research and scientific papers
Green synthesis of halogenated thiophenes, selenophenes and benzo[b]selenophenes using sodium halides as a source of electrophilic halogens
Kesharwani, Tanay,Giraudy, Krystal A.,Morgan, Jordan L.,Kornman, Cory,Olaitan, Abayomi D.
, p. 638 - 641 (2017/01/25)
Herein, we report the first synthesis of chlorinated benzo[b]selenophenes via environmentally friendly electrophilic chlorocyclization reaction using “table salt” as a source of “electrophilic chlorine” and ethanol as a solvent. In addition, the synthesis
Copper(II)-mediated intramolecular cyclization of (Z)-chalcogenoenynes: Synthesis of 3-halochalcogenophene derivatives
Barancelli, Daniela A.,Schumacher, Ricardo F.,Leite, Marlon R.,Zeni, Gilson
experimental part, p. 6713 - 6718 (2012/01/04)
We present our results on the cyclization of (Z)-chalcogenoenynes mediated by copper(II) salts to afford 3-halochalcogenophenes in satisfactory yields through an intramolecular 5-endo-dig cyclization. The methodology was carried out using CuCl2
