685570-02-9Relevant articles and documents
3-Iodoselenophene derivatives: a versatile substrate for Negishi cross-coupling reaction
Schumacher, Ricardo F.,Alves, Diego,Brand?o, Ricardo,Nogueira, Cristina W.,Zeni, Gilson
, p. 538 - 542 (2008)
3-Iodoselenophene derivatives undergo a direct Negishi cross-coupling reaction with several organozinc compounds in the presence of a catalytic amount of Pd(PPh3)4 in THF at room temperature. This cross-coupling reaction proceeded cl
Electrophilic cyclization of (Z)-selenoenynes: Synthesis and reactivity of 3-iodoselenophenes
Alves, Diego,Luchese, Cristiane,Nogueira, Cristina W.,Zeni, Gilson
, p. 6726 - 6734 (2008/02/11)
(Chemical Equation Presented) We present here our results of the electrophilic cyclization reaction of (Z)-selenoenynes with different electrophiles such as I2, ICl, PhSeBr, and PhSeCl. The cyclization reaction proceeded cleanly under mild reac
Hydroselenation of alkynes by lithium butylselenolate: An approach in the synthesis of vinylic selenides
Zeni, Gilson,Stracke, Marcelo P.,Nogueira, Cristina W.,Braga, Antonio L.,Menezes, Paulo H.,Stefani, Helio A.
, p. 1135 - 1138 (2007/10/03)
Vinylic selenides were prepared in good yields by hydroselenation of alkynes with lithium butylselenolate generated by reaction of n-butyllithium with elemental selenium. The regio- and stereochemistry of the hydroselenation depend on the nature of the su