1353248-68-6Relevant articles and documents
Preorganized frustrated lewis pairs
Bertini, Federica,Lyaskovskyy, Volodymyr,Timmer, Brian J. J.,De Kanter, Frans J. J.,Lutz, Martin,Ehlers, Andreas W.,Slootweg, J. Chris,Lammertsma, Koop
, p. 201 - 204 (2012)
Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu2PCH 2BPh2 with H2, CO2, and isocyanates and supported computationally.