1353266-02-0

Basic information

• Product Name: di(μ-chloro)bis[4,4-dimethyl-2-(ortho-(4,6-diisopropylphenylamido)phenyl)-2-oxazoline]dipalladium(II)
• CAS NO: 1353266-02-0
• Molecular Weight: 982.738
• Mol File: 1353266-02-0.mol

Chemical Properties

• CAS DataBase Reference: di(μ-chloro)bis[4,4-dimethyl-2-(ortho-(4,6-diisopropylphenylamido)phenyl)-2-oxazoline]dipalladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: di(μ-chloro)bis[4,4-dimethyl-2-(ortho-(4,6-diisopropylphenylamido)phenyl)-2-oxazoline]dipalladium(II)(1353266-02-0)
• EPA Substance Registry System: di(μ-chloro)bis[4,4-dimethyl-2-(ortho-(4,6-diisopropylphenylamido)phenyl)-2-oxazoline]dipalladium(II)(1353266-02-0)

Safety Data

• Hazardous Substances Data: 1353266-02-0(Hazardous Substances Data)

Upstream product

• 1353265-94-7 (η2-acetato)[4,4-dimethyl-2-(ortho-(4,6-diisopropylphenylamido)phenyl)-2-oxazoline]palladium(II) 
• 7647-14-5 sodium chloride 

Relevant articles and documents

Synthesis, structural studies, and catalytic application of palladium complexes containing anilido-oxazolinate ligands

A series of palladium anilido-oxazolinate complexes 1-8 prepared from ligand precursors HNArOxa [ortho-C6H4(NHAr)(4,4-dimethyl- 2-oxazoline) where Ar = 2,4,6-trimethylphenyl, HNPhTriMeOxa; 2,6-diisopropylphenyl, HNPhDiiPrOxa; phenyl, HNPhHOxa; 2-methoxyphenyl, HNPhOMeOxa; 2-methylthiophenyl, HNPh SMeOxa] is reported. Treatment of HNArOxawith 1.1 equiv. Pd(OAc) 2 afforded palladium(II) acetate complexes (NPhTriMeOxa) Pd(I·2-OAc) (1) and (NPhDiiPrOxa) Pd(I·2-OAc) (2) as monomeric complexes, [(NPh HOxa)Pd(OAc)]2 (3) as an anilido-bridged dinuclear complex, [(NPhOMeOxa)Pd(OAc)]2 (4) as an acetate-bridged dinuclear complex, and (NPhSMeOxa)Pd(OAc) (5) as a monomeric complex. The reactions of 2, 4, and 5 with an excess of NaCl(aq.) in acetone yielded palladium(II) chloride complexes, [(NPhDiiPrOxa)Pd(Cl)] 2 (6) as a chloro-bridged dinuclear complex, (NPhOMeOxa) Pd(Cl) (7) as a monomeric complex, [(NPhOMeOxa)Pd(Cl)]2 (7′) as an anilido-bridged dinuclear complex, and (NPhSMeOxa) Pd(Cl) (8) as a monomeric complex. The crystal and molecular structures of 1-8 are reported, and their application towards Suzuki and Heck reactions with a wide range of aryl halides has been examined. Copyright