1353547-14-4

Basic information

• Product Name: methyl 3-acetyl-4-hexanamidobenzoate
• Synonyms: methyl 3-acetyl-4-hexanamidobenzoate
• CAS NO: 1353547-14-4
• Molecular Weight: 291.347
• Mol File: 1353547-14-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 3-acetyl-4-hexanamidobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-acetyl-4-hexanamidobenzoate(1353547-14-4)
• EPA Substance Registry System: methyl 3-acetyl-4-hexanamidobenzoate(1353547-14-4)

Safety Data

• Hazardous Substances Data: 1353547-14-4(Hazardous Substances Data)

Upstream product

• 142-61-0 Hexanoyl chloride 
• 111714-47-7 3-acetyl-4-aminobenzoic acid methyl ester 

Relevant articles and documents

Synthesis of 4-quinolones via cyclocondensation of substituted ortho-amidoacetophenones: A refit to the camps cyclization by applying trimethylsilyl trifluoromethanesulfonate/triethylamine

A modification of the classical Camps cyclization is described. A series of substituted 4-quinolone derivatives is prepared via trimethylsilyl trifluoromethanesulfonate/triethylamine induced cyclocondensation of substituted ortho-amidoacetophenones. The process shows a broad substrate scope and allows selective preparation of 2-aryl- and 2-alkyl-substituted 4-quino-lones. Enantiopure starting materials react without loss of optical purity using the modified conditions. Subsequent transformations of the products involving preparation of a 4-quinolyl nonaflate and O-selective methylation are also described. Georg Thieme Verlag Stuttgart · New York.