1353548-26-1Relevant articles and documents
Synthesis and structural characterization of organotin(IV) carboxylates based on different heterocyclic substituents
Geng, Wen-Qian,Zhou, Hong-Ping,Cheng, Long-Huai,Hao, Fu-Ying,Xu, Guo-Yi,Zhou, Fei-Xia,Yu, Zhi-Peng,Zheng, Zheng,Wang, Jian-Qing,Wu, Jie-Ying,Tian, Yu-Peng
, p. 738 - 747 (2012/03/12)
Six novel organotin(IV) carboxylates have been successfully synthesized, namely, the polymer (C6H5)3Sn(L1) ∞ (1) [HL1 = 4-imidazolyl benzoic acid], the mononuclear (C6H5)3Sn(L2) (2) [HL2 = 4-pyrazolylbenzoic acid], (C6H5)3Sn(L3)·CH3OH (3) [HL3 = 4-triazolylbenzoic acid] and (C6H5) 3Sn(L4) (4) [HL4 = 4-tetrazolyl benzoic acid] and the tetranuclear [(n-Bu2Sn)4(L2)2O2(OCH 3)2] (5) and [(n-Bu2Sn)4(L3) 2O2(OCH3)2] (6). X-ray diffraction analyses show 1D infinite chain of polymer 1, single molecular structures of isomorphous complexes 2 and 4, single molecule structures of complex 3 containing solvent CH3OH molecule and similar ladder-type structures of complexes 5 and 6. The photoluminescence of ligands and 1-6 were also measured in the solid state at room temperature.