1353585-99-5Relevant articles and documents
E- and Z-Stereoselectivity in the preparation of enamides from glycidyl sulfonamides and carbamates
Brown, Jack A.,Chudasama, Vijay,Giles, Melvyn E.,Gill, Duncan M.,Keegan, Philip S.,Kerr, William J.,Munday, Rachel H.,Griffin, Karen,Watts, Andrew
, p. 509 - 511 (2012/02/01)
Treatment of glycidyl sulfonamides with LDA delivers the corresponding enesulfonamide with good selectivity for the E-isomer, whereas the corresponding carbamates exhibit selectivity for the Z-enecarbamate. An E1cB elimination mechanism proceeding from a