1353649-45-2

Basic information

• Product Name: C₁₇H₂₉ClO
• Synonyms: C₁₇H₂₉ClO
• CAS NO: 1353649-45-2
• Molecular Weight: 284.87
• Mol File: 1353649-45-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₇H₂₉ClO(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₇H₂₉ClO(1353649-45-2)
• EPA Substance Registry System: C₁₇H₂₉ClO(1353649-45-2)

Safety Data

• Hazardous Substances Data: 1353649-45-2(Hazardous Substances Data)

Upstream product

• 931-48-6 2-cyclohexylacetylene 
• 36727-29-4 isononanoyl chloride 

Relevant articles and documents

Iridium-catalyzed addition of aroyl chlorides and aliphatic acid chlorides to terminal alkynes

Iridium complexes show high catalytic activity in intermolecular additions of acid chlorides to terminal alkynes to afford valuable (Z)-β-chloro- α,β-unsaturated ketones. Ligands in the catalytic system play a crucial role in this reaction. An N-heterocyclic carbene (NHC) is an efficient ligand for the addition of aroyl chlorides, while dicyclohexyl(2-methylphenyl) phosphine (PCy2(o-Tol)) is indispensable for the reaction of aliphatic acid chlorides. The addition reactions proceed regio- and stereoselectively with suppression of decarbonylation and β-hydrogen elimination, which have been two major intrinsic problems in transition-metal-catalyzed reactions. Stoichiometric reactions of active iridium catalysts with aroyl chlorides and aliphatic acid chlorides are carried out to gain insights into the reaction mechanisms.