1353684-45-3

Upstream product

• 1353684-01-1 9-oxo-9H-thioxanthene-1,4-diyl bis(trifluoromethanesulfonate) 
• 1353684-31-7 1-(4-methoxyphenyl)-9-oxo-9H-thioxanthen-4-yl trifluoromethanesulfonate 
• 63503-60-6 3-chlorophenylboronic acid 
• 14992-80-4 1,4-dihydroxy-9H-thioxanthen-9-one 
• 5720-07-0 4-methoxyphenylboronic acid 

Relevant academic research and scientific papers

Suzuki-Miyaura reactions of the bis(triflates) of 1,3- and 1,4-dihydroxythioxanthone. Electronic and steric effects on the site-selectivity

The palladium(0)-catalyzed Suzuki cross-coupling reactions of the bis(triflates) of 1,3- and 1,4-dihydroxythioxanthone afforded various aryl-substituted thioxanthones. While the Suzuki reactions of the bis(triflate) derived from 1,3-dihydroxythioxanthone proceeded by site-selective attack in favor of position 3, the reactions of the bis(triflate) of 1,4- dihydroxythioxanthone proceeded in favor of position 1. The site-selectivity is controlled by steric and electronic parameters.